Can transparent wood replace plastic and glass?

Can transparent wood replace plastic and glass?


Conventionally, wood is used in making furniture, construction and as a source of fire. But now, researchers are exploring the possibility of making wood transparent as an eco-friendly alternative to glass.

Researchers are looking to tune wood’s optical, thermal, mechanical and ionic transport properties by chemically and physically modifying its naturally porous structure and chemical composition. “Such modifications can be used to produce sustainable, functional materials for various emerging applications such as automobiles, construction, energy storage and environmental remediation,” says a paper titled ‘Engineered Wood’, published in Annual Reviews.

Transparent wood is created when wood from the fast-growing, low-density balsa tree is treated to a room temperature, oxidising bath that bleaches it of nearly all visibility. It is then penetrated with a synthetic polymer called polyvinyl alcohol (PVA), creating a product that is virtually transparent, according to the US Department of Agriculture.

In 1992, German scientist Siegfried Fink developed the initial transparent wood, a creation that researchers have refined further. In simple words, it is made by removing the lignin (a polymer that’s found in the cell walls of plants) from wood and replacing it with clear plastic materials.

The advantages of using wood over plastic are numerous. Apart from being abundant and renewable, wood is also an eco-friendly alternative to high-carbon footprint materials.

Despite advancements, the widespread use of natural wood is constrained by its opaque appearance, modest mechanical strength compared with metals like aluminium and steel, and elevated thermal conductivity when compared to foams and wools, according to researchers.

Adopting transparent wood could also be cost-effective. It offers about five times better thermal efficiency than glass, reducing energy expenses.

For a green future

In recent research, scientists created transparent wood using acrylic derived from natural basswood and examined its resistance to various elements. The research paper “Comprehensive assessment of transparent wood degradation” was published in 2023 by Igor Wachter et al of University of Technology in Bratislava, Slovakia. The transparent wood showed strong resistance to fungi. In fire tests, it ignited later and produced less harmful carbon monoxide than regular wood. The material also experienced changes in colour and transmittance when exposed to UV radiation, with significant changes occurring in the first few hours.

The challenges identified by the researchers include ensuring durability against fire, microorganisms and weathering, along with the need to scale up production and reduce environmental impact. To overcome these challenges, efforts are directed towards exploring stability improvement methods, optimising production processes, and adopting environmentally friendly chemical approaches.

Now, is transparent wood market-ready?

Researchers say not yet. “Government incentives for engineered wood to displace petroleum-based polymers will accelerate market penetration.”

However, ‘transparent wood’ is not problem-free. A study at the University of Maryland highlighted three important challenges.

It says, the first challenge is creating high-performance materials with good product durability and service life. Currently, most modification methods have focused on enhancing the performance of wood. Little research has been conducted on the durability of wood-based materials when exposed to fire, microorganisms, water, or weathering. “This is a crucial factor to consider due to the hydrophilicity and biodegradability of the wood components.”

The second challenge is scaling up fabrication and reducing manufacturing and installation costs. One approach to tackle this is the use of high temperature and pressure to facilitate the diffusion of chemicals in the wood microchannels, resulting in a more homogeneous modification. The third challenge the paper mentions is that of reducing environmental pollution. Toward this goal, researchers are investigating the use of green solvents for wood de-lignification such as deep eutectic solvents or organic acid, which lead to much lower environmental impacts.





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This new nuclear fuel can guarantee India’s green energy transition

This new nuclear fuel can guarantee India’s green energy transition


An invention by an American company, set up by a person of Indian origin, is making waves in the nuclear establishment of North America. If adopted in India, it can guarantee green energy security for the subcontinent by fast-tracking the use of Thorium in nuclear reactors.

India has the world’s largest reserves of Thorium, estimated at 1.07 million tonnes, enough to last over a century. If India uses this Thorium, it can then produce enough green energy and easily turn net-zero by its target date of 2070.

However, Thorium is a fertile material and not a fissile material. This means, it must be paired with Uranium-235 or Plutonium-239 to be used as fuel in a reactor. As neutrons from these fissile materials bombard Thorium, it mutates into Uranium-233, which is also a fissile material. So, to use the Thorium in India, you need sufficient stocks of Uranium-235 (which India has very little of), or Plutonium-239 (which is produced using Uranium-235). So, the question has been, how to use Thorium with minimal use of (precious) Uranium.

Mehul Shah

This is where the invention of Mehul Shah, Founder and CEO of Clean Core Thorium Energy, comes in. The Chicago-based company has developed (and patented) a fuel, which is a mix of Thorium and Uranium of a certain level of enrichment, called HALEU (High Assay Low Enriched Uranium). Clean Core calls this concoction ANEEL (Advanced Nuclear Energy for Enriched Life) — named so to honour one of India’s foremost nuclear scientists, Dr Anil Kakodkar.

Gamechanger

ANEEL can be used in the existing Pressurized Heavy-Water Reactors (PHWRs), an indigenous reactor system that is the workhorse of India’s nuclear fleet. India has 18 PHWR reactors of a total capacity of 4,460 MW and is building ten more of 700 MW each.

If pursued, Clean Core’s ANEEL fuel can prove to be a game-changer for India. According to the World Nuclear Association, most of the current reactors run on uranium fuel enriched up to 5 per cent Uranium-235. HALEU is Uranium enriched to more than 5 per cent but less than 20 per cent. It is needed for many of the advanced nuclear reactor designs under development. “HALEU is not yet widely available commercially. At present only Russia and China have the infrastructure to produce HALEU at scale. Centrus Energy, in the US, began producing HALEU from a demonstration-scale cascade in October 2023,” says the Association. With uncertain commercialisation timelines, HALEU suppliers have remained cautious on scaling capacity due to demand-side risk.

Perfect pair: Clean Core’s nuclear fuel bundle made from Thorium and HALEU

Perfect pair: Clean Core’s nuclear fuel bundle made from Thorium and HALEU

However, with Clean Core’s near-term timeline to commercialisation, the company can help strengthen the demand-side confidence for HALEU suppliers.

India’s approach to Thorium utilisation has been to make a Thorium blanket around uranium or plutonium reactors, so that as the reactor produces energy, it also converts thorium into uranium-233. However, ANEEL provides an easier and quicker alternative for the deployment of thorium leveraging imported HALEU.

Nuclear waste reduction

Furthermore, in utilising this fuel, reactor operators can enjoy a dramatic reduction in nuclear waste volume and operating costs.

Another significant advantage is the inherent operating characteristics of the ANEEL fuel bundle — it lasts much longer and burns more efficiently. Its burn-up is 60,000 MW-days per tonne, compared with the 7,000 MW-days per tonne of the conventional natural uranium fuel in PHWRs. This higher burn-up significantly impacts the waste volumes and economics of reactor operations compared with the currently used natural uranium.

For example, in an existing Indian 220 MW PHWR, while using natural uranium fuel, an average of eight bundles would need to be replaced daily for the rest of the reactor’s operating life of 60 years. That is about 1,75,000 bundles used over the life of a reactor. With the ANEEL fuel, an average of only one such bundle would need to be replaced daily resulting in about 22,000 bundles used over the lifetime of the reactor. This leads to significant reduction in waste generation and cost savings.

Due to the inherent benefits of using thorium, the spent ANEEL fuel cannot be used for weapons — a source of comfort for foreign uranium suppliers and reactor operators, says Mehul Shah.

With all these benefits, Shah believes that ANEEL-powered 220 MW Indian PHWR can fill a growing need for clean, baseload energy production, as highlighted by the pledge to triple nuclear capacity by more than 20 countries at the recently held COP28.

Other countries are also showing interest in using ANEEL. “This is the first-of-its-kind nuclear fuel, in that it combines HALEU and thorium in proprietary unique compositions that can drive a global clean energy future,” says Dr Sean McDeavitt, Director of the Nuclear Engineering and Science Center and professor in the Department of Nuclear Engineering at Texas A&M University.

In April 2023, Canadian Nuclear Laboratories signed a MoU with Clean Core “to further the development and deployment of Clean Core’s ANEEL fuel,” according to a press release. Under the MoU, CNL would support Clean Core’s activities, including R&D and licensing.





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Atmanirbhar Carbon Credits Standards: India’s Milestone Move towards a Sustainable Future

Atmanirbhar Carbon Credits Standards: India’s Milestone Move towards a Sustainable Future


n a groundbreaking move, the Ministry of Power in India introduces Atmanirbhar Carbon Credits Standards through amendments to the Carbon Credits Trading Scheme. This initiative not only benefits Indian companies by saving processing costs but also opens doors for overseas entities to earn carbon credits based on Indian standards. Explore the significant steps taken towards establishing a robust Indian carbon market and contributing to the global decarbonization effort.





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IIT-Bombay’s superalloy for ultra-efficient boilers

IIT-Bombay’s superalloy for ultra-efficient boilers


Researchers at IIT Bombay have tested an oxidation-resistant, nickel-based superalloy that is able to stand the extreme temperatures and pressures of the most efficient boilers in coal-fired thermal power plants.

While further work is required to be done for validation of ‘Alloy 617’, the conclusions of the research work mark a milestone in the evolution of the Advanced Ultra Super Critical (AUSC) technology.

In boiler technology, efficiency—a measure of how much of energy contained in the fuel is converted into useful energy—increases as the temperature and pressure of steam go up. In the subcritical boilers, these are about 570 degrees and 175 bars, with 33-37 per cent efficiency. Then come the supercritical boilers with 570 degrees, 250 bars and 38-42 per cent efficiency. Supercritical boilers are the norm in the industry today. Ultra supercritical boilers (620 degrees, 275 bars, 42-46 per cent) are just around the corner. But the most efficient boilers are the AUSCs, of 710 degrees, 320 bars, with more than 50 per cent efficiency.

As India gears up to add another 87 GW of coal-fired power plants by 2032, it is imperative to go in for the best technologies, which produce more energy from the same amount of coal.

For some time now, there is a talk about bringing in the Advanced Ultra Super Critical (AUSC) boilers, where the ultra-hot steam zips through the turbines with more energy, generating more electricity. The AUSCs have about 30 per cent less carbon footprint than the subcritical boilers.

The problem in developing these very high efficiency boilers is ‘materials’. You need to make boilers whose walls and tubes can stand such tortuously high temperatures and pressure.

The IIT Bombay research team, headed by Prof VS Raja of the Department of Metallurgical Engineering and Material Science, tested the commercially available alloy, called Alloy 617, for boiler applications. This heat-resistant alloy of nickel, iron and cobalt can withstand high temperatures. The team performed tests in a simulated Advanced Ultra Supercritical (AUSC) environment, which was designed to replicate the extreme temperature and pressure conditions that exist in a coal-fired power plant.

“IIT Bombay was invited by the government of India to undertake the study. It was a national project in mission mode and the Government of India wanted to go ahead with thermal power plants with higher thermal efficiency,” says Prof Raja.

New territory

Until now, Alloy 617 has remained relatively unexplored for potential use in AUSC technology due to difficulties in creating a test loop that simulates the extreme conditions of an AUSC steam oxidation test loop, says an article on IIT-B’s website. Previous studies have been limited and inconclusive, with the steam temperature and pressure conditions examined not exceeding 670oC and 27 MPa, respectively and water chemistry not controlled precisely.

Speaking to Quantum, Prof Raja said that the objective of the research was to understand the alloy for AUSM applications. While the alloy has been found to be able to withstand harsh temperatures and pressures, more work would need to be done to make a functional boiler, he said.

The researchers also tested another alloy, Alloy 740, which showed better mechanical strength, but oxidised earlier. Asked whether India has the capability to manufacture Alloy 617, Prof Raja says the public sector alloy company, MIDHANI (Mishra Dhatu Nigam) might be able to do it.

The alloy for the experiments was locally fabricated by Symec Engineers and this is a first-of-its-kind study in India. “Very few such setups exist across the world and this is the only setup in India,” says Prof Raja.

Reacting to this development, boiler design expert M R Ganesan, a former Executive Director at BHEL, said that the IIT Bombay research findings are very significant and useful for the development of better boilers. Ganesan also wanted BHEL to revive the ‘magneto hydro dynamics’ project, which can handle coal gas at temperatures of 4000oC and generate power with much less carbon footprint.





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Return of CSP to aid round-the-clock green power

Return of CSP to aid round-the-clock green power


Concentrated Solar Power (CSP), which had been almost elbowed out of business by the low-cost solar PV, is now making a comeback. Quantum learns that recently NTPC, the state-owned power generating company, sent out feelers to various companies asking if they would be interested in putting up CSP plants; and the response was overwhelming.

“CSP with thermal storage can provide 24×7 renewable energy at less than ₹3 per kWhr,” says Rajan Varshney, Deputy General Manager at NTPC, in a LinkedIn post.

While producing electricity from CSP is one option, a few others are being explored in the scientific and business worlds. CSP works by concentrating sun’s rays onto a point to generate heat. Why convert the heat to steam and producing electricity? Why not use the heat directly?

NTPC wants CSP companies to produce and sell hot steam, which reduces the load on the boilers to heat up the steam—implying burning lesser coal and smaller carbon footprint. Some others are suggesting that CSP heat can be used to produce hydrogen.

Prof KS Reddy and Saurabh Mohite of the Heat Transfer and Thermal Power Laboratory, Department of Mechanical Engineering, IIT-Madras, have recently published the results of their research into photo-electrolysis of water using heat from CSP.

Their method is simple. Use the heat produced by the CSP plant to heat zinc oxide, splitting it into zinc and oxygen. Put the zinc into water, the metal will grab the oxygen in the water to form zinc oxide again, which leaves hydrogen in the water. The second reaction—hydrolysis of zinc—releases heat, about 104 KJ/mole. This is lesser than the 456 KJ/mole demanded by the first reaction, but there is some additional heat kick-back  from the second reaction. In a paper in Energy Conversion and Management, Reddy and Mohite say that the method yields significantly more hydrogen. “Though CSP is an old system, it is gaining popularity among researchers for hydrogen production due to its high temperature applications in the range of 500–2000°C,” the paper noted.

Further, it doesn’t have to be zinc oxide—any metal oxide will work, though each one would need to be studied for its yield.

CSP technologies come in different forms—Parabolic trough collectors (PTC), linear fresnel reflectors, parabolic dish collectors and solar power towers (SPT). In 2020, the world had 6.5 GW of CSP, most of it was PTC. However, solar power towers are gaining more attention as they are able to achieve high solar concentration factors — over 1,000 suns — and operate at higher temperatures, 1000o C and above. “SPT presents a higher room for improvement and a bigger potential for cost decrease due to a higher solar-to-electric efficiency, higher energy densities, a low-cost solar field, less maintenance and oil-free plants with lower environmental impact,” says Javier Bigorri et al of the National Renewable Energy Center, Navarre, Spain.

Experts now are suggesting combining CSP plants with solar PV and wind, so that the same system is used for storing electricity from multiple sources. The conventional way of storing CSP energy has been molten salts, but more advanced CSP-linked storage technologies are emerging—(i) Sensible Heat Storage including novel molten salts, sensible packed-bed thermocline and liquid metals; (ii) Latent Heat Storage: phase change materials packed-bed thermocline and (iii) Thermochemical Energy Storage: hydrides, hydroxides, carbonates and redox reactions.

In sum, CSP is padding up for its second innings.





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Orange River

Orange River


Orange River is a 2,432-km long river of southern Africa—but we are not talking about that here.

We are talking about a river that has turned orange in the Alaskan wilderness, which still remains untouched by civilisation.

In an article on ‘Why rivers in Alaska are turning orange’, the Scientific American turns the focus lights on to a disturbing effect of climate change.

Climate change is the result of global warming, or the Earth catching fever, due to mankind spewing greenhouse gases into the atmosphere. Talks about limiting global warming to 1.5oC have been going around for a while now, but that is only the average. The Kobuk Valley National Park has warmed by 2.4oC since 2006—that is like person with a fever of 102.92oF. The increasing warmth is melting polar permafrost and is turning the rivers orange.

Scientists theorise that as the permafrost thaws, a few things begin to happen. The earth below holds incredible amounts of dead plants and animals from a distant era before the ice-age, as well as oxidised iron. Microbes like bacteria de-oxidise (or, reduce) the iron oxide, leaving the pure metal behind, which is soluble in water. This iron is carried by groundwater into oxygenated streams, where the iron rusts again, giving the streams a disagreeable, orange colour.

Well, there might just be some other explanation. But it is still linked to loss of permafrost, which is undeniably due to global warming.





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