Engineering a thermally stable perovskite solar cell

Engineering a thermally stable perovskite solar cell


Scientists at the International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Hyderabad, have engineered methylammonium lead iodide (MAPI) to attain thermal stability by incorporating guanidinium iodide and moisture stability through surface passivation using 5- amino valeric acid iodide. The scientists also fabricated mini modules for use in real-time applications.

The modified MAPI exhibits a 2D/3D encapsulant layer at the perovskite surface, which helps the perovskite attain high moisture and temperature stability. The engineered MAPI films exhibit excellent temperature (150-plus degrees C) and ambient stability (more than 59 days) when compared with traditional MAPI films.

This stable perovskite was used as an absorber in carbon-based perovskite solar cells and was successfully integrated with road reflectors to power the LEDs, which were used to charge commercial 1.2V batteries. It can be powered under a full sun and also functions at diffused light, which is key in niche applications.

Organic light harvester

A new nanogenerator device developed for harvesting light energy using organic material has the potential to power wearable devices on the go. The device can generate current and voltage from minute amounts of heat or light that fall on it.

The scientific community is exploring various ways to meet the ever-growing demand for energy. Harnessing energy from the nano regime is a prime area of focus, and energy generation from organic materials holds great potential for sustainability.

Scientists at the Institute of Advanced Study in Science and Technology (IASST), in Guwahati, have developed the nanogenerator device for harvesting light energy using organic material.

The exploration of energy materials by IASST led to the synthesis of an organic energy material called polyaniline-rubrene and the fabrication of an organic pyroelectric nanogenerator (OPyNG), says an IASST press release.

The device features polycrystalline graphene oxide and polyaniline-rubrene forming a rectifying junction. In this configuration, the polyaniline-rubrene thin film serves as the photoactive layer responsible for generating charge carriers. The pyroelectric effect of the device owes to the light-induced change in spontaneous polarisation occurring in the ultra-thin oxidised surface layer of the polyaniline-rubrene thin film.





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Battling tuberculosis in speed mode

Battling tuberculosis in speed mode


India accounts for a quarter of tuberculosis cases worldwide. However, recent research by the Department of Community Medicine and Family Medicine, All India Institute of Medical Sciences, Bhubaneswar, suggests that the country has made remarkable strides in combating this deadly disease and stands a chance of eliminating it by 2025, five years ahead of the global target.

Since 1962, when the National Tuberculosis Programme (NTP) was launched, the strategies to tackle this communicable disease have evolved over time, culminating in the establishment of the National Tuberculosis Elimination Programme (NTEP) in 2020 with the stated aim of eradicating TB from the country.

There are multiple challenges along the way, topped by limited budget allocation. As the AIIMS-Bhubaneswar research paper, titled ‘India marching towards TB elimination: How far we are’, states: “There are some challenges which India needs to overcome to achieve its target five years ahead of the [United Nations] Sustainable Development Goals. Insufficient budget, inadequate diagnostic facilities, under-reporting, low success rate, high dropout rate, social stigma are some of the major challenges.”

Shortage of funds hinders the adoption of comprehensive strategies, and the expansion of diagnostic facilities and treatment options. The study calls on the government to prioritise TB elimination through higher budget allocation.

Early detection

Enhanced diagnostic capability is another key aspect of the battle against TB, the research notes. It is essential to equip healthcare facilities with advanced diagnostic technologies to accurately detect TB and determine drug resistance. Newer tools such as the Gene Xpert MTB/ RIF assay and MERM (medical event reminder monitor) can revolutionise TB diagnosis and choice of treatment.

Similarly, early detection of the disease is vital for higher success rates. “For any disease to be eliminated, the idea is to identify all active cases at the earliest, prevent cross-infection from active cases to other people, treat the patient completely, and ensure good follow-up,” says Dr Anantha Krishnan, an infectious disease expert at Prashanth Hospitals, Chennai.

Social factors

TB has two forms: pulmonary (affecting the lungs) and extra-pulmonary. It can affect any part of the body, making diagnosis challenging. Accurate diagnosis through proper use of tools must be followed by the initiation of anti-tuberculosis treatment (ATT), ensuring patient’s compliance and completion of ATT, and adequate follow-up care.

Equally important is the need to address the social, economic, cultural, and nutritional vulnerabilities in the fight against tuberculosis. Factors such as overcrowding, migration, social stigma, and poor nutritional status contribute to the spread and persistence of the disease.

“To prevent tuberculosis, focusing on the overall health and immune system is essential. Dietary tips include incorporating a variety of fruits and vegetables, opting for whole grains, including pulses and legumes, consuming dairy products, and staying hydrated with traditional beverages,” says Madhavi Avate, a nutritionist and lactation counsellor.

Role of private sector

Sounding a note of caution, Dr Krishnan says, “India’s TB treatment is not centralised as it is not uniform. Nearly 50 per cent of TB patients are diagnosed in the private sector and the rest by the government sector. Although the private sector reporting of tuberculosis has gone up from 4 per cent to 25 per cent, there is a huge gap due to underreporting, so I do not think India is in any position to eliminate tuberculosis by 2025.”

The inclusion of private healthcare providers in TB elimination efforts can vastly expand the reach of diagnostic and treatment services, the study recommends. Policies, regulation, and advocacy are needed to ensure delivery of adequate treatment and care services.

An added challenge is TB’s co-infection with diseases like HIV and diabetes. Integrating TB services with existing health programmes can optimise resources and improve outcomes for those with dual burdens.





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How ISRO is working on next generation rockets 

How ISRO is working on next generation rockets 


With seven straight successful launches, the LVM-3 rocket that took the 3.9-tonne Chandrayaan-3 spacecraft to the drop-off point 180 km above the earth has proved to be a reliable one. Now ISRO, India’s space agency, is working on upgrading it further so that it can carry 6-tonne heavy payloads up to Geostationary Transfer Orbits (GTO).

But a rocket like the LVM-3 is good only up to a point. To go further and faster, the LVM-3 will not do. Nor is LVM-3 quite the thing for bringing down the cost of launching satellites, for which purpose, you would need reusable launch vehicles and vehicles that use cheaper fuels. 

Also read: Chandrayaan-3 launch: ‘How beautiful that was!’ comments ISRO Chairman Somnath

The good news is, ISRO is working on a bunch of rocket technologies- some of which are sure to hit commercial service in a decade. 

Here is a quick look at some of them. 

Air-breathing rockets 

ISRO’s Chairman, Sreedhara Panicker Somanath, calls air-breathing rockets “a dream”. Air-breathing rockets have scramjet engines that can accelerate by themselves during their flight through the atmosphere, conserving chemical fuels for use later. 

To put it simply, ‘scramjet’, or supersonic ram jets, have funnel-like openings on their bodies, with the mouth of the funnel facing the direction of flight. During flight, air enters the funnels at very high speeds and gets compressed as it passes through the thin end of the funnel.

The compressed air is fed into the combustion chamber where it meets the vaporised fuel (as in an automobile engine) and self-ignites. This creates a thrust. In a ramjet, air is fed into the combustion chamber at speeds lesser than the speed of sound (subsonic); in a scramjet engine, it happens at supersonic speeds. 

Also read: Chandrayaan-3 launch: Indian-origin CEOs in Silicon Valley are over the moon

Ramjets and scramjets are commonplace in missile technology. India’s Brahmos missile is fitted with ramjets; a supersonic variant has a scramjet engine. However, scramjets have not been successfully used in rockets, which need to travel not at supersonic speeds (1.2 to 5 Mach), but at hypersonic speeds (above Mach 5). 

One Mach is the speed of sound, roughly 1,225 km per hour. 

Some years ago, ISRO successfully tested an air-breathing engine on a sounding rocket, but it is now working on a bigger engine (called air-frame integrated air breathing engine) that can sustain longer durations in flight. The engine is actually under manufacture for testing, but even as this is happening, ISRO is in talks with the industry for producing the rockets.

LOx methane engines 

Methane engines are hot today, they take rocketry to the next level. The advantages are well known. Liquid methane—essentially LNG—is not as potent a fuel as hydrogen. But the temperature at which it needs to be kept in rocket tanks is much higher than hydrogen–about minus 161°C compared with minus 253°C for hydrogen. 

Moreover, it does not leak—the methane molecule is a much bigger one than hydrogen. And, methane is a lot cheaper and abundantly available. 

Also read: Chandrayaan-3: Some questions and answers 

So, every space company is eyeing methane rockets—or, Liquid Oxygen-Methane (or LOx)–because you need an oxidizer for methane to burn. Yet, liquid methane rockets are not yet commonplace, because quite a few challenges must be first overcome.

One is the problem of ‘coking’, or ‘soot deposition’. As the gas approaches the combustion chamber, some of it splits into carbon and hydrogen and the carbon gets deposited on the insides of the tubes as soot, which creates a host of problems such as combustion instability. Researchers are trying to tackle this problem by developing soot-resistant materials, such as ceramics, and adding specially designed additives to the fuel.  

Also, the industry needs to get familiar with this technology to develop confidence to put in money into manufacturing. 

While practically everybody (SpaceX, Blue Origin, Rocket Lab, etc.) is working on methane rockets, the first to do a proper space flight with one is the Chinese company Landscape, whose Zhuque-2 rocket achieved the feat on July 11—three days before the Chandrayaan-3 launch.  

Somanath had told this writer in 2019 that ISRO was working on a LOx methane (or, Methalox) rocket, but it is still under development. Its idea is to convert a cryogenic engine into a LOx-methane.  

Also read: Chandrayaan and the Tamil connect

Jayant Patil, Member of Executive Council of Management, L&T, says that LOx-methane engines are ideal for reusable rockets. Compared with kerosene, liquified methane has 20 per cent lower relative density with the same calorific value and a slightly higher specific impulse—therefore, the fuel is a fifth less heavy than kerosene with a better thrust.  

HAVA-India’s space shuttle 

ISRO is also working on a space shuttle—a vehicle that can deliver payloads to orbit. It is called HAVA, for Hypersonic Air-breathing Vehicle Assembly, which can deliver payloads of up to 500 kg to low earth orbit. Based on the ‘re-usable launch vehicle’ technology, which itself is under development, the HAVA is a space-shuttle-like vehicle, which will fly on the back of a GSLV, deliver the payload, and return to land on an airstrip, like an airplane. A prototype is expected to be ready for testing in a few years. 

These are just a few technologies that ISRO is working on, but there are many more—such as vertical take-off and landing (V-TOL), electric propulsion, nuclear propulsion, not to speak of areas like additive manufacturing in space and research into functional materials. 





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Google unveils NFT policy for Play Store as token interest wanes

Google unveils NFT policy for Play Store as token interest wanes


Google’s decision to allow developers to expand the ways nonfungible tokens can be used in their games on the Play Store was met with a collective sigh of relief on crypto Twitter. 

NFT investors, who have for months watched the prices of their collections fall and interest in this colorful corner of the digital-asset market wane, see the changes in Google’s policy as a sign that the market is not dead yet.

“We’re so back,” said Kyle McCollom, a co-founder at a Brooklyn-based crypto startup. 

ALSO READ | Meta to shut down testing NFTs on Instagram, Facebook

“You thought NFTs were dead?” tweeted Daniel Borovik, creator of multiple collections listed on OpenSea, the largest marketplace by volume for nonfungible tokens. 

In a blog post published Wednesday, Alphabet Inc.’s Google said it will allow developers to offer games where players can buy, sell and earn tokenised digital assets—like nonfungible tokens—subject to specific guidelines. 

Plummeting values

NFTs once ranked among the crypto industry’s hottest assets, attracting the attention of celebrities like Madonna, Justin Bieber and superstar DJ Steve Aoki. 

But in the months since the collapse of FTX, the digital assets most closely associated with cartoonish pictures of apes have since seen their value and popularity plummet. Monthly global sales volumes for NFTs fell 38% to $653 million in June compared with the same period last year, according to blockchain data provider CryptoSlam. 

ALSO READ | WazirX shuts NFT marketplace amid crypto downturn

Google has had a mixed strategy on blockchain and crypto: Google Play still bans crypto mining apps from its marketplace, while Google Cloud in 2021 teamed up with Dapper Labs, the creator of the NBA Top Shot digital collectibles.

The move to clarify its policies also further aligns Google with main rival Apple Inc., which introduced new App Store guidelines in October on crypto trading, as well as on the use of NFTs within apps and games. Both Google and Apple have been lambasted by the crypto and gaming industries for high fees on in-app transactions.

Brian Armstrong, Chief Executive Officer of crypto exchange Coinbase, publicly criticised Apple last year over these in-app transaction rules, citing their “app store monopoly.”

Google Play’s updated guidelines, which go into effect December 7, say that games can support transactions involving tokenized assets under the platform’s existing Real-Money Gambling, Games, and Contests policy. Developers will have to follow specific rules, such as ensuring that the value of an NFT is made clear to a player at the time of purchase. 





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New graphite anode alternative

New graphite anode alternative


A newly-developed high-capacity anode that is extremely stable at high rates, could be a potential alternative to the commercial graphite anode. It can be used as a substitute for safe, stable and rapid-charging next-generation LIBs with higher storage capacity. A team at the Centre for Nano and Soft Matter Sciences (CeNS), Bengaluru, led by Dr HSS Ramakrishna Matte, has developed this high-capacity anode. The anode is a ternary FeOOH-rGO-MnO2 composite anode made from a simple low-temperature synthetic procedure.

The work, which is published in ACS Applied Energy Materials, showcases the stable performance of the anode, wherein it delivered capacities of 9,56,842, and 688 mAh g-1 (milliampere-hours per gram mass-unit of specific capacity) at 1, 2, and 5 A g-1 respectively for 200 cycles along with cycling stability of 900 mAh g-1 at 1 A g-1 for 100 cycles.

Take a liberal pinch of salt

Can we ever add as much salt as we like to our food without affecting our health? Yes, we can—the answer lies in low sodium salt. The Central Salt and Marine Chemicals Research Institute (CMSCRI), Bhavnagar, has developed a low sodium salt called ‘Saloni K’. It is a mixture of sodium chloride and potassium chloride,“useful for those who have been advised to eat less common salt,” CMSCRI says.

Saloni K is made from Slicornia brachiata, a high salt-accumulating and edible oil bearing plant and Kappaphycus alvarezii, a red algae.

The know-how for cultivation of the plants and making Saloni K is market ready. While it has been transferred to a local small-scale company, CMSCRI is open to technology transfer.

Bone-friendly implants

The problem with putting metal implants into our bodies is that they take most of the mechanical load, leaving little for the bones around them to bear. Though it may sound very kind to the bones, it is not actually so. Bones need mechanical load to grow strong and because of the “stress shielding” offered by the metal implants, the natural bones around them die out and dissolve.

Researchers at IIT-M have found a solution to this problem by using a technique called ‘multi-phase topology optimisation’—a simulation technique that determines the optimal distribution of two or more different materials in a combination under thermal and mechanical loads. Prof Sourav Rakshit and S Rajaram of the Department of Mechanical Engineering have used ‘macroscale optimisation’ and ‘microscale optimisation’ on the pelvic bone, with good results, according to a paper produced by them.

Solar cell shows 26% efficiency

The National Centre for Photovoltaic Research and Education at IIT-Bombay has developed a solar cell that combines a perovskite solar cell and a conventional crystalline silicon cell. The cell has been demonstrated an efficiency of over 26 per cent. Comparatively, the best cells in the market have efficiencies of 22 per cent. “We have fabricated a stable 4T (four terminal) Si/perovskite tandem solar cells which provides outstanding stability in the dark as well as continuous heating conditions” says Prof Dinesh Kabra, who led the research at IIT-B. The cell could be “the gateway for use in niche applications like building integrated photovoltaics (BIPV)”, says Kabra.





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Ancient world’s ‘Ivory Man’ turns out to be ‘Ivory Lady’

Ancient world’s ‘Ivory Man’ turns out to be ‘Ivory Lady’


At a time when Indiana ‘Indy’ Jones is back in our midst and ‘archaeology’ is buzzing in our heads, a new scientific technique to determine the sex of a long-deceased and skeletonised individual has been tried out with success.

To tell whether a 5,000-year-old skeleton is a ‘he’ or a ‘she’ is almost impossible unless you can get hold of some genetic material, which is not always available. Therefore, “archaeologists have for decades struggled with sex estimation of poorly preserved human remains,” say the authors of a Spanish research whose work recently revealed that the ‘Ivory man’, a powerful individual buried in a lavish tomb 5,000 years ago, was actually a woman.

The ancient individual was apparently of a high social order and was buried with a number of sumptuary items produced with exotic items like ivory, rock crystal and amber, and a large ceramic plate that had traces of wine and cannabis.

To make the sex determination, scientists Marta Cintas-Peña, et al, of the Department of Prehistory and Archaeology, University of Seville, Spain, looked into the tooth enamel of the ‘Ivory man’. Through the analysis of sexually dimorphic amelogenin peptides in the enamel, they have established that the most socially prominent person of the Iberian Copper Age (c. 3200–2200 BC) was a female, not male as previously thought.

The technique uses proteomics and can provide highly reliable sex determinations even for poorly preserved human skeletons, the researchers say.





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